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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 34, 2004 - Issue 6
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Original Articles

Facile and Selective Synthesis of Chloromethylpyridines and Chloropyridines Using Diphosgene/Triphosgene

, , , &
Pages 1097-1103 | Received 18 Sep 2003, Published online: 21 Aug 2006
 

Abstract

Diphosgene and triphosgene in the presence of amines were found to be an excellent chlorinating agents with high selectivity for the preparation of chloromethylpyridines and chloropyridines from picoline‐N‐oxides and pyridine‐N‐oxides respectively.

#IICT Communication No: 030808.

Acknowledgment

The authors thank the Director‐IICT and Head Organic Division. PN thanks CSIR and BG thanks UGC for fellowship awards.

Notes

#IICT Communication No: 030808.

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