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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Volume 35, 2005 - Issue 5
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Original Articles

Ligand Induced Stereoisomers Revealed in Copper(II) Complex of Nitrolawsone Oxime: EPR and Electronic Spectral Studies

S. Y. Rane Department of Chemistry, University of Pune, Pune, IndiaCorrespondence[email protected]
,
E. M. Khan Department of Chemistry, Abeda Inamdar Senior College Camp, Pune, India
,
Ah. Khursheed Department of Chemistry, Abeda Inamdar Senior College Camp, Pune, India
&
S. Salunke‐Gawali Department of Chemistry, University of Pune, Pune, India
Pages 343-353 | Received 19 Jan 2005, Accepted 18 Feb 2005, Published online: 15 Feb 2007
 
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Amphi‐syn stereoisomers with 62:38 compositional ratio existing in 3‐nitrolawsoneoxime [S.Y. Rane et al., 1990] leads to two configurational forms in its copper (II) complex 1 viz. [Cu(NO2‐LwOx)2] · 3H2O. The D4h:D2h geometries of 1 have been detected in 70:30 ratio from solution EPR spectra. Line width alternation effect with superimposition of metal‐ligand hyperfine splits lead to anisotropic magnetic parameters. Best fitted bonding parameters of 1 are compared with O∧O and N∧O donor complexes.

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