SPECTROSCOPIC PROPERTIES AND ELECTRONIC STRUCTURE OF [CuCl(L-PROLINATO)(H₂O)]

ABSTRACT

[CuCl(L-Prolinato)(H₂O)] was prepared. Its electronic absorption spectrum and photoacoustic spectrum were recorded at the room temperature. A semi-empirical method of ligand-field-theory PLFT was utilized to calculate the d-d transition energy. According to the results, the spectrum was explained satisfactorily.

Keywords:

• Electronic absorption spectrum
• PA spectrum
• [CuCl(L-Prolinato)(H₂O)] electronic structure
• PLFT

ACKNOWLEDGMENTS

The authors are grateful to Mr. Liu Hongpu, for the assistance with the electronic absorption spectrum measured. This work was partly supported by the NATIONAL NATURE SCIENCE FOUNDATION OF P.R. CHINA.