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21st Century Coe Program, Nagaoka University of Technology, Hybridized Materials with Super Functions 2005. Edited by I. Nishiguchi, M. Takata, K. Ishizaki and S. Kamado

Photorefractivity in polymer dissolved liquid crystal composites composed of low-molecular-weight nematic liquid crystals and copolymer comprising mesogenic side groups

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Pages 158-164 | Received 17 Aug 2004, Accepted 10 Nov 2004, Published online: 16 Feb 2005
 

Abstract

This paper describes the photorefractive effect of the liquid crystalline composite materials comprising low-molecular-weight nematic liquid crystals (L-LC), copolymer with mesogenic side groups and a small amount of photosensitizer. Copolymers with four kinds of mesogenic side groups were investigated with respect to the compatibility between the L-LC and the copolymer and the photorefractivity of the composites. Two of them could be miscible with L-LC and the composite exhibited LC phase even though the copolymer itself did not show a LC phase. High gain coefficients (> cmK1) under the low applied dc electric field (<1V/mm) was observed when the composites showed a mesophase without any macroscopic phase separation.

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