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Analytical Letters Volume 41, 2008 - Issue 3
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Electrochemistry

Voltammetry of Potassium Octyl Xanthate at Mercury Electrode

K. Dhanalakshmi Department of Chemistry, Sri Venkateswara University, Tirupati, India
,
B. Prasad Department of Chemistry, Sri Venkateswara University, Tirupati, India
,
N. V. S. Naidu Department of Chemistry, Sri Venkateswara University, Tirupati, IndiaCorrespondence[email protected]
,
G. Suresh Department of Construction Engineering, National Tiwan University of Science & Technology, Tiwan
&
K. Saraswathi P.G. Department of Chemistry, P.B. Siddhartha College of Arts & Sciences, Vijayawada, A.P., India
Pages 437-443 | Received 24 Jul 2007, Accepted 01 Sep 2007, Published online: 11 Feb 2008
 
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Abstract

Electrochemical studies of potassium octyl xanthate at the mercury electrode reveal that the product of the anodic reaction is strongly adsorbed at the mercury surface as indicated by a prewave. The adsorbed film greatly affects the characteristics of the anodic wave of xanthate in aqueous medium. The current of total wave is proportional to the concentration of xanthate from 0.32 to 1.6 mM.

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