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Original Articles

Application of Crown Ether in Chemical Analysis Extraction of Copper(II)-Zincon Chelate Anion with Crown Ether Complex

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Pages 1431-1439 | Received 18 Aug 1980, Accepted 10 Oct 1980, Published online: 24 Feb 2007
 

Abstract

Crown ether-potassium ion complex extracts selectively copper-zincon anion complex as ion-pairs into chloroform phase in the presence of copper-zincon and zinc-zincon chelate anion, whereas quarternary ammonium ion extracts both anions. By measuring the absorbance of the chloroform phase at 615 nm, copper in the presence of zinc has been determined spectrophotometrically. The composition of extracted species was estimated to be Cu2+-zincon4−-(KL+)2.

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