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Analytical Letters Volume 15, 1982 - Issue 15
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Original Articles

Crown Ethers for Chemical Analysis: A Review

Masaki Yoshio Department of Industrial Chemistry, Saga University, Saga, 840, Japan
&
Hideyuki Noguchi Department of Industrial Chemistry, Saga University, Saga, 840, Japan
Pages 1197-1276 | Published online: 06 Dec 2006
 
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Abstract

Natural macrocvclic compounds, such as valinomycin, are attractive to analysts who have interest in the high selectivity of potassium ion as compared to sodium ion. This selectivity in alkali metal ions was not found in other ligands. Pedersen synthesized many crown ethers [1] and published his result that dibenzo-18-crown-6 (DB18C6) had a larger affinity to potassium than other alkali metals. Since then, these ligands and related compounds have held great interest for physical, inorganic and biochemists.

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