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Original Articles

Molecular Imprinted Polymers Prepared by Electropolymerization of Ni-(Protoporphyrin IX)

, , , , , & show all
Pages 1809-1824 | Received 08 Jan 1998, Accepted 25 Apr 1998, Published online: 22 Aug 2006
 

Abstract

The features of combining a chemically modified electrode (CME) with an artificial receptor system, prepared by imprinting electropolymerized [Ni

(Protoporphyrin IX) dimethyl ester] [Ni-(PPIX)] in the presence of nitrobenzene, were studied. The responses of the modified glassy carbon electrode towards template molecules were analyzed by cycling over the nitrobenzene reduction wave. The specific signal was much higher than the non-specific one which demonstrates the selectivity of such a system.

This approach has potential for preparation of selective polymeric films on the surface of different transducers.

∗ Visiting scientist on leave from Institute of Molecular Biology and Genetics, Academy of Sciences of Ukraine, 252143, Kiev, Ukraine.

∗∗ Visiting scientist on leave from Universidad de Buenos Aires, Junin 956, Buenos Aires 1113, Argentina.

Notes

∗ Visiting scientist on leave from Institute of Molecular Biology and Genetics, Academy of Sciences of Ukraine, 252143, Kiev, Ukraine.

∗∗ Visiting scientist on leave from Universidad de Buenos Aires, Junin 956, Buenos Aires 1113, Argentina.

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