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Combustion Science and Technology Volume 162, 2001 - Issue 1
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Original Articles

Spectroscopic Studies of Low Pressure Opposed Flow Methane/Air Flames Inhibited by Fe(CO)5, CF3Br, or N2

R.R. SKAGGS U.S. Army Research Laboratory, Aberdeen Proving Ground, MD, 21005View further author information
,
K. L. McNESBY U.S. Army Research Laboratory, Aberdeen Proving Ground, MD, 21005
,
R.G. DANIEL U.S. Army Research Laboratory, Aberdeen Proving Ground, MD, 21005
,
B. HOMAN U.S. Army Research Laboratory, Aberdeen Proving Ground, MD, 21005
&
A.W. MIZIOLEK U.S. Army Research Laboratory, Aberdeen Proving Ground, MD, 21005
Pages 1-17 | Received 11 Jan 1999, Accepted 09 Sep 1999, Published online: 19 Apr 2007
 
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Abstract

Hydroxyl radical (OH) is measured using laser induced fluorescence in reduced pressure, non-premixed, opposed flow CH4/air flames inhibited by either N2, CF3Br, or Fe(CO)5. Emission spectroscopy is used to qualitatively monitor OH for each inhibited flame as well as to characterize the structure of a Fe(CO)5 inhibited flame. For the flames to which CF3Br and Fe(CO)5are added, the OH population decreases approximately proportional to the amount of inhibitor agent added. OH populations decrease faster for flames inhibited by Fe(CO)5 than for flames inhibited by CF3Br.

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Notes on contributors

R.R. SKAGGS

[email protected]

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