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Ferroelectrics Volume 240, 2000 - Issue 1
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Modulated structures

Relations between relaxor behavior and cationic substitutions in lead-free BaTiO3 derived ceramics

Annie Simon ICMCB - CNRS, 87 avenue Dr A. Schweitzer, 33608, PESSAC, France
&
Jean Ravez ICMCB - CNRS, 87 avenue Dr A. Schweitzer, 33608, PESSAC, France
Pages 1601-1608 | Received 12 Jul 1999, Published online: 26 Oct 2011
 
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Abstract

Relaxor lead-free BaTiO3 derived ceramics were prepared and characterised by various physical studies. The relaxor characteristics depend on the substitution rate and on the type of ionic substitution: they are favoured by a stronger composition deviation from BaTiO3 and by heterovalent substitutions in the octahedral crystallographic site of the perovskite.

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