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SECTION C: FERROELECTRICS, RELAXORS AND PHASE TRANSITIONS

Influence of Porosity on Polarisation and Electrical Properties of Hydroxyapatite Based Ceramics

, , , , , & show all
Pages 168-176 | Received 26 Aug 2008, Published online: 20 Sep 2010
 

Abstract

This paper studies the effect of porosity on the electrical properties and polarisation behaviour of hydroxyapatite based ceramics prepared in both dense and porous form. Porosity was introduced into the hydroxyapatite using either burnt-out polymer spheres to produce isolated pores or using polymer foams to create interconnected porosity. The samples were sintered in water vapour at 1300°C and polarised at 400°C with a dc voltage of 3kV/cm applied for 1 hour. Thermally stimulated depolarisation current measurements were used to investigate the degree of polarisation of the hydroxyapatite ceramics and dielectric spectroscopy used to measure the ac conductivity of the materials at the polarisation temperature. The porous materials were successfully polarised and the presence of a high surface area to volume ratio in the porous samples was thought to increase the level of polarisation.

Acknowledgments

The authors wish to show their appreciation and gratitude to the EPSRC (EP/D013798/1) and Great Western Research (HEFCE), UK for their funding of this research.

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