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Ferroelectrics Volume 397, 2010 - Issue 1
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Original Articles

Systematization of Simple and Binary Silicates According to Relationship “Composition– Structure–Property”

B. I. Kidyarov Laboratory of Nonlinear Resonant Processes and Laser Diagnostics, Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090, Russia
&
V. V. Atuchin Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090, Russia
Pages 169-176 | Received 22 Sep 2009, Accepted 20 Jan 2010, Published online: 23 Jun 2010
 
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Abstract

It is shown that acentric silicate crystals are positioned into three intersected ellipses of «acentricity» on the plane of the oxide bond lengths plane. The dependence of nonlinear optical property of silicates on the shortest chemical bond length L(Si-O) is non-monotonous. The suggested crystal chemistry analysis is useful for searching new acentric silicate crystals.

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