Abstract
In this work, we investigate the imprint behavior of lead-rich Pb(Zr, Ti)O3 (PZT) thin films deposited onto copper-coated Kapton® substrates by piezoresponse force microscopy. As-deposited films, consisting of a mixture of PZT and lead and zirconium oxides, had a strongly imprinted polarization state with a polarization vector pointing toward the film surface. Above a threshold field of about 10 V/μm, a steeply increasing piezoelectric response without hysteresis was obtained. With increasing voltage cycling, the threshold field increases and a one-sided piezoresponse hysteresis is obtained. The described imprint behavior is related to initially trapped charge carriers and their detrapping under voltage cycling.
Acknowledgments
This work was supported by the German Research Foundation (DFG) - Grant GE 779/18-1, by the DAAD-GRICES Grant D/07/13640, by the Academy of Science of the Czech Republic—Grants KAN301370701 and AV0Z10100522, and by the Grant Agency of the Czech Republic—Grants 202/09/J017.