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Ferroelectrics Volume 494, 2016 - Issue 1
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Original Articles

Effect of Sn:Ti ratio on electric properties in lead lanthanum zirconate stannate titanate ceramics

Q. W. LouShanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai University of Electric Power, Shanghai, China
,
T. ZengShanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai University of Electric Power, Shanghai, ChinaCorrespondence[email protected]
,
X. F. ChenKey Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, China
,
H. L. ZhangNational Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, China
,
X. L. DongKey Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, China
&
G. S. WangKey Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, China
Pages 61-67 | Accepted 28 Mar 2015, Published online: 25 Feb 2016
 
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ABSTRACT

The effect of Sn:Ti ratio with large range from 55:3 to 10:48 on the phase structure and electrical properties of Pb0.97La0.02(Zr0.42Sn0.58-xTix)O3 ceramics has been investigated. A sequence of phase transitions were analyzed by the variation of P-E hysteresis loops with increasing temperature. The antiferroelectric (AFE)/ferroelectric (FE) occurred at room temperature (RT) when Sn:Ti ratio is between 50:08 and 40:18 with the Zr content of 0.42, which improves the lanthanum doped ternary phase diagram.

Funding

This work was financially supported by the National Nature Science Foundation of China (51202273, 11204304 and U1330128). This research also has been supported by Innovation Program of Shanghai Municipal Education Commission (No. 13YZ106) and by Science and Technology Commission of Shanghai Municipality. (No: 14DZ2261000).

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