Abstract
The damping constant (linewidth) of the LA mode is calculated as a function of temperature for the incommensurate (INC) phase of quartz by using the models of the pseudospin-phonon (PS) coupled and the energy fluctuation (EF). For this calculation, the observed linewidth () data are used at
and
from the literature. Close to the incommensurate phase between the
and
phases of quartz, the observed
and the frequency shifts (
) are also analyzed by the power-law formula for both pressures (
and
). By using the
and
the inverse relaxation time (
) is predicted as a function of temperature (
and
) in the incommensurate phase of quartz and the values of the activation energy (
) are deduced. Our calculated
from both models (PS and EF) explain adequately the observed behavior of the linewidth of the LA mode in the incommensurate phase of quartz. Also, our predicted
can be compared with the measurements in the INC phase of this molecular crystal.