Optical activity of [N(CH₃)₄]₂ZnCl₄

Kazuya Saito Kagami Memorial Laboratory for Material Science and Technology, Waseda University, 2–8–26 Nishiwaseda, Shinjuku-ku, Tokyo, 169, Japan

Nobuko Takahashi Kagami Memorial Laboratory for Material Science and Technology, Waseda University, 2–8–26 Nishiwaseda, Shinjuku-ku, Tokyo, 169, Japan

Itaru Kamiya Kagami Memorial Laboratory for Material Science and Technology, Waseda University, 2–8–26 Nishiwaseda, Shinjuku-ku, Tokyo, 169, Japan

Jinzo Kobayashi Kagami Memorial Laboratory for Material Science and Technology, Waseda University, 2–8–26 Nishiwaseda, Shinjuku-ku, Tokyo, 169, Japan; Research Development Corporation of Japan

Abstract

All the components of gyration tensor and birefringence of [N(CH₃)₄]₂ZnCl₄ were measured in its paraelectric, incommensurate and ferroelectric phases by using the high accuracy universal polarimeter (HAUP). Only one component, g₂₃, was found to appear both in the incommensurate and ferroelectric phases, but all the other components zero in the three phases.

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Optical activity of [N(CH₃)₄]₂ZnCl₄

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Optical activity of [N(CH₃)₄]₂ZnCl₄