Dissolution, Transport and Reaction at a DICY/DGEBA Interface

Abstract

The curing of an epoxy consisting of the solid hardener dicyandiamide (DICY) and the resin diglycidyl ether of bisphenol A (DGEBA) is studied in a system consisting of a tablet of DICY embedded in liquid DGEBA. Dissolution of DICY within the liquid DGEBA in combination with the transport of dissolved DICY from the tablet border into DGEBA and the chemical reaction of both reactants is studied by scanning Brillouin microscopy and infrared spectroscopy. Scanning Brillouin microscopy demonstrates the spatial and temporal evolution of the static and dynamic hypersonic properties in the course of curing in the vicinity of the DICY tablet. Infrared spectroscopy performed on epoxy pieces extracted from the final sample at different distances from the tablet surface give information about the spatial evolution of the curing process. The results achieved by both techniques are finally combined to yield a better understanding of the curing of DICY-based epoxies, which transform upon curing from strongly heterogeneous systems towards increasingly homogeneous systems.

KEYWORDS:

• Brillouin microscopy
• Curing
• DGEBA
• DICY
• Dissolution
• Transport

Notes

Presented in part at the 4th World Congress on Adhesion & Related Phenomena (WCARP-IV), held in Arcachon, France, 26–30 September 2010.

Present address of Martine Philipp is Lehrstuhl für funktionelle Materialien E13, Physik Department, Technische Universität München, Carching, Germany.