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Original Articles

Novel Waterborne Polyurethane Adhesives Based on Ag@SiO2 Nanocomposites

, &
Pages 437-456 | Received 29 Jul 2013, Accepted 11 Sep 2013, Published online: 10 Mar 2014
 

Abstract

In this work, the use of silver-based silica nanocomposites (Ag@SiO2) was proposed to inhibit the microorganism growth of waterborne polyurethane adhesives. For that purpose, colloidal silver nanoparticles were prepared and embedded in a SiO2-based matrix in order to decrease the silver aggregation tendency. The protection of AgNPs with silica was also intended to improve the stability of the adhesive toward metallic particles. Last but not least, Ag@SiO2 provides safer handling of the silver nanoparticles due to their immobilisation within the silica matrix. Colloidal silver was prepared by the Creigthon method using NaBH4 as a reducing agent and polyvinylpyrrolidone (PVP) as a stabilising agent. The coating of the AgNPs by the silica matrix was achieved through a modified Stöber process. The stability of the AgNPs in different amino-based catalysts for the silica matrix synthesis was evaluated in order to successfully obtain silver–silica core-shell nanocomposites. After that, AgNPs and Ag@SiO2 nanocomposites were incorporated in a waterborne polyurethane adhesive and the chemical, thermal adhesion and antimicrobial properties were evaluated.

ACKNOWLEDGMENTS

The authors thank Synthesia Española who kindly supplied the polyol used for the synthesis of the waterborne adhesives.

Notes

*st, stretching; δ, bending; sy, symmetric; asym, non-symmetric; δoop, bending out the plane; bonded ordered urea, C˭O of urea bonded to both N–H groups of a nearby urea moiety; bonded disordered urea, C˭O of urea bonded to only one N–H group nearby an urea o urethane.

*T g was determined as temperature at that inflexion point.

Color versions of one or more of the figures in the article can be found online at www.tandfonline.com/gadh.

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