Advanced search
Publication Cover
Journal of Macromolecular Science: Part A - Chemistry Volume 11, 1977 - Issue 5
Journal homepage
141
Views
119
CrossRef citations to date
0
Altmetric
Original Articles

Poly-2,3- and 2,7-Bicyclo[2.2.1]hept-2-enes: Preparation and Structures of Polynorbornenes

Norman G. Gaylord Gay lord Research Institute Inc. New Providence, New Jersey, 07974
,
Achyut B. Deshpande Gay lord Research Institute Inc. New Providence, New Jersey, 07974
,
Broja M. Mandal Gay lord Research Institute Inc. New Providence, New Jersey, 07974
&
Michael Martan Gay lord Research Institute Inc. New Providence, New Jersey, 07974
Pages 1053-1070 | Received 31 Dec 1976, Accepted 25 Dec 1976, Published online: 05 Dec 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The polymerization of norbornene in the presence of either radical catalysts having a short half-life at the polymerization temperature or ethylaluminum dichloride yields a saturated polymer having a rearranged structure with 2,7 linkages. Polymerization in the presence of either Pd(C6H5CN)2Cl2 or Ziegler-Natta catalysts containing TiCI4 and A1R3 or R2 A1C1 yields a saturated polymer with 2,3 linkages.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Order Reprints Request Corporate Permissions

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

Request Academic Permissions

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.

Related Research Data

C-C bridged Ni(II) for norbornene and styrene (co)polymerization
Source: (:unav)
Nickel (II) complexes supported by a fluorinated β-diketiminate backbone ligand: synthesis, catalytic activity toward norbornene polymerization, and the oxygenated species
Source: Wiley
Metal Complexes for the Vinyl Addition Polymerization of Norbornene: New Compound Classes and Activation Mechanism with B(C6F5)3/AlEt3
Source: Wiley
Vinyl polymerization of norbornene with bis(imino)pyridyl nickel(II) complexes
Source: Wiley
Dihalogeno(diphosphane)metal(II) complexes (metal = Co, Ni, Pd) as pre-catalysts for the vinyl/addition polymerization of norbornene – elucidation of the activation process with B(C6F5)3/AlEt3 or Ag[closo-1-CB11H12] and evidence for the in situ formation of “naked” Pd2+ as a highly active species
Source: (:unav)
Catalytic addition polymerization of norbornene and its derivatives and copolymerization of norbornene with olefins
Source: Pleiades Publishing Ltd
Janus tricyclononene polymers bearing tri(n-alkoxy)silyl side groups for membrane gas separation
Source: Royal Society of Chemistry (RSC)
Nickel N-heterocyclic carbene complexes in the vinyl polymerization of norbornene
Source: Wiley
Ni(II) and Pd(II) Complexes
Source: Wiley
Controlled Vinyl-Type Polymerization of Norbornene with a Nickel(II) Diphosphinoamine/Methylaluminoxane Catalytic System
Source: Wiley

Linking provided by 

Related research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.