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Original Articles

Experimental Investigations of the Conditions for the Formation of the Liquid Crystalline State of Polymers

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Pages 283-296 | Received 05 Aug 1980, Published online: 20 Apr 2011
 

Abstract

The diagrams of state for concentrated PBG solution in coordinates relating volume fraction-geometric asymmetry and volume fraction-temperature are investigated. The order parameter for macromolecules in the anisortropic phase is dettermined. The experimental data compare with the existing theoretical models for th formation of the liquid crystalline state in solutions of stiff polymer molecule. It is shown that experimental data are in good quantitative agreement with the Flory's lattice model.

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