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Original Articles

A New Theory of the Equilibrium Properties of Nematic Liquid Crystals

Pages 79-104 | Received 29 Jan 1981, Accepted 25 Jun 1981, Published online: 14 Oct 2011
 

Abstract

A new theory of nematics applicable to dense systems of rodlike particles is presented. The formulation endeavors to avoid the use of a lattice, steric effects involved in the dense packing of mesogenic molecules being treated in a manner consistent with this advance. The theory has many similarities with the well-known Flory approach and shares the same analytic simplicity.

The results of the theory give improved estimates of the athermal limit, the order parameter at the transition and the latent entropy for nematics.

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