Synthesis, Polymerization and X-ray Structure (Monomer and Polymer) of the Unsymmetrical Diacetyle-Ne pTS-pFBS

M. Bertault Groupe de Physique Cristalline, UA au CNRS 040804, Université de Rennes I, Campus de Beaulieu, 35042, Rennes, Cedex, France

J. Canceill Chimie des Interactions Moléculaires, ER du CNRS 285, College de France, 11, Place Marcelin-Berthelot, 75005, Paris, France; Groupe de Physique Cristalline, UA au CNRS 040804, Université de Rennes I, Campus de Beaulieu, 35042, Rennes, Cedex, France

A. Collet Chimie des Interactions Moléculaires, ER du CNRS 285, College de France, 11, Place Marcelin-Berthelot, 75005, Paris, France; Groupe de Physique Cristalline, UA au CNRS 040804, Université de Rennes I, Campus de Beaulieu, 35042, Rennes, Cedex, France

L. Toupet Groupe de Physique Cristalline, UA au CNRS 040804, Université de Rennes I, Campus de Beaulieu, 35042, Rennes, Cedex, France

Abstract

Some preliminary results on the new unsymmetrical diacetylene pTS-pFBS are presented. pTS-pFBS is the disubstituted molecule R‒C˭C‒C˭C‒R’ where R is CH₃-Ph-SO₃-CH₃O and R’ is F-Ph-SO₂-CH₂O, R and R’ being respectively the side groups of the well known symmetrical diacetylenes pTS and pFBS. Synthesis, crystallization and thermal polymerization data are described. The X-ray crystal structures of monomer and polymer pTS-pFBS had been determined at 143 K and are discussed in terms of particular reflections.

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Synthesis, Polymerization and X-ray Structure (Monomer and Polymer) of the Unsymmetrical Diacetyle-Ne pTS-pFBS

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Synthesis, Polymerization and X-ray Structure (Monomer and Polymer) of the Unsymmetrical Diacetyle-Ne pTS-pFBS

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