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Liquid Crystals

Synthesis and Properties of Thermotropic Liquid Crystals with Two Non-Mesogenic Units and a Flexible Central Spacer

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Pages 79-87 | Received 10 Mar 1988, Accepted 26 Sep 1988, Published online: 04 Oct 2006
 

Abstract

The synthesis of new di-Schiff bases with two non-mesogenic units and a flexible central spacer (‒CH2‒CH2‒) in their structure is reported. The mesomorphic properties of the compounds were investigated by differential scanning calorimetry (DSC) and polarizing microscopy.

The Schiff bases derived from the aldehydes were mesogenic while those derived from the ketones were not. A comparative study of their different mesogenic behavior was carried out to establish the influence of molecular structure on liquid crystal properties.

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