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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 99, 2001 - Issue 18
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RESEARCH NOTE

Analytical model of equation of state for polydisperse fluid of adhesive spherical particles

Pages 1613-1616 | Received 11 Apr 2001, Accepted 08 May 2001, Published online: 18 Nov 2009
 

Abstract

An analytical model of the equation of state is presented for the polydisperse fluid of adhesive colloidal particles. The model is based on the mean-spherical approximation solution of the Ornstein-Zernike equation for a multicomponent hard sphere Yukawa fluid in which the Yukawa tails are sufficiently short range and strong. In particular, assuming that distributions of diameters and ‘charges’ of particles are described by the Schulz function, the analytical expressions for the compressibility and the pressure for the intrinsically polydisperse fluid are given in terms of simple functions of the packing fraction, the adhesion parameter and the Schulz distribution parameter.

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