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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 102, 2004 - Issue 8
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Original Articles

Identification of single charge transfer channels in –N2 collisions by translational energy spectroscopy

, , &
Pages 765-770 | Received 18 Dec 2003, Accepted 22 Mar 2004, Published online: 21 Aug 2006
 

Abstract

Single charge transfer reactions in the collision of

ions at a laboratory energy of 2 keV with N2 were observed using translational energy spectroscopy (TES). Within the limitation of the energy analyser resolution (∼ 8/q eV, q being the ionic charge number), the translational energy spectrum shows a single broad charge transfer peak with a rich substructure. The latter looks like a conglomeration of closely spaced channels clumped together, corresponding mainly to charge transfer into excited states, rather than into the ground state. The reaction channel assignments were made using data available in the literature. Our findings are in accord with a recent experimental result, but there are no theoretical calculations to compare our experimental measurements with.

Notes

This work forms part of the Ph.D Thesis of the first author

Additional information

Notes on contributors

T. K. Rai Dastidar

This work forms part of the Ph.D Thesis of the first author

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