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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 104, 2006 - Issue 15
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Original Articles

New analysis of the D(4)1Π u state of Na2 using polarization labelling spectroscopy

A. Grochola Institute of Experimental Physics, v, ul. Hoża 69, 00-681 Warsaw, Poland
,
W. Jastrzebski Institute of Physics, Polish Academy of Sciences, Al.Lotników 32/46, 02-668 Warsaw, Poland
&
P. Kowalczyk Institute of Experimental Physics, v, ul. Hoża 69, 00-681 Warsaw, PolandCorrespondence[email protected]
Pages 2569-2573 | Received 10 Mar 2006, Accepted 10 May 2006, Published online: 10 Jan 2007
 
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Abstract

The D(4)1Π u state in the Na2 molecule is experimentally investigated by using the polarization labelling spectroscopy technique. The D band system is observed under rotational resolution providing information of rovibrational levels in the D state up to v,′ = 72 (that covers 85% of the potential well depth). A set of Dunham coefficients is deduced to fit the spectroscopic data and the potential curve of the D state is constructed using the Inverted Perturbation Approach method.

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