Abstract
When the number of strongly correlated electrons becomes larger, the single-reference coupled-cluster (CC) CCSD, CCSDT, etc. hierarchy displays an erratic behaviour, while traditional multi-reference approaches may no longer be applicable due to enormous dimensionalities of the underlying model spaces. These difficulties can be alleviated by the approximate coupled-pair (ACP) theories, in which selected diagrams in the CCSD amplitude equations are removed, but there is no generally accepted and robust way of incorporating connected triply excited (
) clusters within the ACP framework. It is also not clear if the specific combinations of
diagrams that work well for strongly correlated minimum-basis-set model systems are optimum when larger basis sets are employed. This study explores these topics by considering a few novel ACP schemes with the active-space and full treatments of
correlations and schemes that scale selected
diagrams by factors depending on the numbers of occupied and unoccupied orbitals. The performance of the proposed ACP approaches is illustrated by examining the symmetric dissociations of the
and
rings using basis sets of the triple- and double-ζ quality and the
linear chain treated with a minimum basis, for which the conventional CCSD and CCSDT methods fail.
GRAPHICAL ABSTRACT
![](/cms/asset/bf2de4fc-3951-44af-86ec-51cd07144249/tmph_a_2057365_uf0001_oc.jpg)
Acknowledgments
We dedicate this article to the memory of the late Professor Lutosław Wolniewicz, whose pioneering work on high-precision molecular quantum mechanics inspired our interest in becoming quantum chemists. One of us (P.P.) would like to thank Professors Stanisław Dembiński, Jacek Karwowski, and Józef Szudy for inviting him to contribute an article to the Special Issue of Molecular Physics commemorating Professor Lutosław Wolniewicz.
Disclosure statement
No potential conflict of interest was reported by the author(s).