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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 28, 1974 - Issue 1
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Original Articles

Potential theory of strong electrolyte solutions using the Bogoliubov-Born-Green-Yvon integral equations

Pages 217-224 | Received 19 Nov 1973, Published online: 22 Aug 2006
 

Abstract

A potential analysis of strong electrolyte solutions is undertaken using the BBGY hierarchy of integral equations. An estimate for the fluctuation potential is found which implies damped oscillatory solutions of the Debye-Hückel potential for κa ⩾ 1·720 (κ = Debye-Hückel constant, a = ionic diameter). The relation to the work of Martynov is also given.

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