Publication Cover
Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 36, 1978 - Issue 4
9
Views
4
CrossRef citations to date
0
Altmetric
Original Articles

The analytic continuation of a group of eigenvalues

Pages 941-972 | Received 28 Feb 1978, Published online: 23 Aug 2006
 

Abstract

The branch point structure of a group of eigenvalues that are functions of some parameter is used to derive a method for their analytic continuation as the solutions of an algebraic equation. The procedure is valid so long as no member of the group branches with the rest of the spectrum. The perturbation series for the total projection operator for the group is derived in a form such that small denominators due to near degeneracy are eliminated. This then allows the continuation of eigenfunctions and properties by diagonalization of the projected hamiltonian. This provides a formalism for nearly degenerate perturbation theory with clear convergence properties. Other treatments may be obtained by suitable choice of a transformation function that relates the group projector to its unperturbed value; it is shown that the function proposed by Kato has useful diabatic properties.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.