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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 37, 1979 - Issue 6
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Original Articles

Calculation of angular distributions in complex angular momentum theories of elastic scattering

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Pages 1703-1712 | Received 08 May 1978, Published online: 23 Aug 2006
 

Abstract

An important practical problem in the application of complex angular momentum techniques to atomic and molecular scattering is the evaluation of Legendre's function of the first kind of complex degree. An exact series representation, that can be summed numerically, has been derived using accelerated convergence techniques. The accuracy of various asymptotic representations for the Legendre function is also investigated. The use of these asymptotic formulae is shown to be valid for most applications of complex angular momentum techniques to atomic and molecular scattering. The asymptotic formulae have a physical interpretation involving backward glories and surface waves.

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