Correlation functions from depolarized Raman and Rayleigh spectra of N₂ at high density and 150 K

Abstract

Orientational correlation functions derived from the rotational and rotovibrational Raman spectra of N₂ at 150 K and 585 amagat are compared with the results of a molecular dynamics simulation available in the literature. The angular momentum correlation function is also estimated from the experimental memory function and compared with the one obtained by simulation. Mean square torques, intermolecular correlations and interaction induced contributions are also discussed.

Work partially supported by C.N.R.

Work partially supported by C.N.R.

Notes

Work partially supported by C.N.R.