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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 48, 1983 - Issue 4
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Original Articles

Application of perturbation theory to the calculation of the dielectric constant of a dipolar hard sphere fluid

A. Tani IBM Research Laboratory, San Jose, California, 95193, U.S.A.; Instituto di Chimica Fisica, Universita di Pisa, via Risorgimento 35, 56100, Pisa, Italy
,
D. Henderson IBM Research Laboratory, San Jose, California, 95193, U.S.A.
,
J.A. Barker IBM Research Laboratory, San Jose, California, 95193, U.S.A.
&
C.E. Hecht Department of Chemistry, City University of New York, Hunter College, New York, New York, 10021, U.S.A.View further author information
Pages 863-869 | Received 23 Aug 1982, Accepted 04 Oct 1982, Published online: 22 Aug 2006
 
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Abstract

Perturbation theory is applied to calculate the dielectric constant of a dipolar hard sphere fluid. The results seem to be fairly good. However, this conclusion can only be stated tentatively because of uncertainties in the computer simulation estimates of the dielectric constant of this fluid.

Additional information

Notes on contributors

C.E. Hecht

Supported in part by NSF Grant No. CHE80-01969.

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Related Research Data

A third and fourth order perturbation theory for dipolar hard spheres
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