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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 50, 1983 - Issue 6
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Original Articles

Collisions and umbilic catastrophes

The hyperbolic umbilic canonical diffraction integral

, &
Pages 1215-1230 | Received 20 Jun 1983, Accepted 01 Aug 1983, Published online: 23 Aug 2006
 

Abstract

Two procedures to evaluate the hyperbolic umbilic canonical diffraction integral, a function that occurs in many applications of semiclassical collision theory and optics, are described. The first is the integration of the various differential equations satisfied by this function. We present schemes to perform the numerical integration and investigate their range of validity. A second algorithm, which evaluates the integral directly by quadrature, is given. Here, attention is focused on the very rapidly oscillating regions of the integrand. The direct quadrature method is shown to be more widely applicable and better suited to numerical computation.

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