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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 54, 1985 - Issue 3
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Original Articles

A theoretical study of Fermi resonance spectra in liquids

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Pages 677-688 | Received 06 Jun 1984, Accepted 21 Sep 1984, Published online: 23 Aug 2006
 

Abstract

Fermi resonance is viewed as an intramolecular coupling of two modes. The set of isolated molecules in which the Fermi resonance occurs is disturbed by the intermolecular interaction. For such a system a derivation of the expression for the vibrational correlation function, which is based on the cumulant expansion theorem, is presented. Applying this general expression we have calculated the Fermi resonance spectra in the fast modulation limit.

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