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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 56, 1985 - Issue 3
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Original Articles

Quantum corrections to the second virial coefficient for hard discs

Pages 701-708 | Received 24 Apr 1985, Accepted 20 Jun 1985, Published online: 22 Aug 2006
 

Abstract

Asymptotic expressions, valid at high temperatures, are obtained for the direct and exchange parts of the second virial coefficient for quantum hard discs. The results are qualitatively similar to those for hard spheres and, in particular, there is a similar exponential suppression of the exchange term with increasing temperature.

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