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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 56, 1985 - Issue 5
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Original Articles

Multiphoton rotational line strength in diatomic molecules between two Hund's case (a) states

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Pages 1165-1174 | Received 03 Jul 1984, Accepted 20 Jun 1985, Published online: 23 Aug 2006
 

Abstract

The n-photon rotational line strength (RLS) in diatomic molecules is studied for transitions between two states which both belong to Hund's case (a). The expression of the n-photon RLS is given for n identical photons linearly polarized and n identical photons circularly polarized, in the Born-Oppenheimer approximation and neglecting rotational contributions to the energies of the intermediate states. The selection rules are also given.

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