Dipole and higher order polarizabilities of the 10-electron systems

Abstract

Static electric polarizabilities were calculated for the 10-electron isoelectronic series OH^-, F^-, NeH⁺ and Mg²⁺ in the LCAO-SCF-MO approximation. All the independent components of all polarizability tensors up to the fourth rank were included in the study. The isotropic components of the fourth order polarizability tensors C, B and γ are, in atomic units, Ȼ = 69.10, 35.19, 1.79 and 0.24, Ƀ = -2286, -552, -6 and -0.3 and = 94600, 12900, 24 and 0.6 for OH^-, F^- NeH⁺ and Mg²⁺, respectively.

Additional information

Notes on contributors

David M. Bishop

Member of the Ottawa-Carleton Chemistry Institute