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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 58, 1986 - Issue 1
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Original Articles

Optics and intermolecular forces

Pages 33-52 | Received 23 Apr 1985, Accepted 15 Nov 1985, Published online: 22 Aug 2006
 

Abstract

The influence of long-range intermolecular forces upon the refractive index and optical rotation of molecular fluids is examined using quantum electrodynamics and many-body theory. An expression for this effect, analogous to the McLachlan formula for the dispersion energy, and involving the molecular polarizability and second hyperpolarizability, is derived in the case of a non-polar fluid.

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