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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 62, 1987 - Issue 1
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Original Articles

Statistical mechanical models of chemical reactions

IV. Solvent effects near the critical point

, &
Pages 65-90 | Received 23 Feb 1987, Accepted 03 Apr 1987, Published online: 22 Aug 2006
 

Abstract

A statistical mechanical model of chemically reactive fluids in an inert solvent exhibiting liquid-gas criticality is studied using analytically solvable integral equation approximations. The model consists of a mixture of three molecular species (A, B and C), two of which (the solutes A and B) can undergo reaction and one of which (the solvent C) is inert. Particular interest centres on the results for the chemical equilibrium obtained near the mixture critical point of the solution.

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