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We report three dimensional classical trajectory studies on the photodissociation dynamics of the Ã
1
B
1 state of H2O prepared by a 193 nm excitation from the (000) or (001) vibrational states of the electronic ground state 
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A
1. Vibrational and rotational distributions of the dissociation fragment OH(X
2II) have been obtained and are in good agreement with experimental results and approximate quantum mechanical results.
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