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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 67, 1989 - Issue 1
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Original Articles

The orientational ordering of a biaxial solute in mixtures of nematic solvents

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Pages 151-160 | Received 07 Sep 1988, Accepted 12 Dec 1988, Published online: 26 Oct 2007
 

Abstract

The two orientational order parameters Szz and Sxx-Syy have been obtained for a biaxial solute, p-xylene, in the liquid crystal solvents N-(4-ethoxybenzylidene)-4'-n-butylaniline (EBBA), ZLI 1132, which is a mixture of 4-(trans-4'-n-alkylcyclohexyl)benzonitriles and 4-(trans-4'-n-heptylcyclohexyl) benzonitrile (PCH7), and in approximately equimolar mixtures of EBBA with either ZLI 1132 or PCH7. It is found that the solute-solvent interaction parameters for the mixtures, which are derived from the order parameters, deviate strongly from values predicted by random mixing. The possible reasons for this unexpected behaviour are discussed.

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