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Molecular Physics
An International Journal at the Interface Between Chemistry and Physics
Volume 68, 1989 - Issue 3
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Preliminary communication

Vapour-liquid equilibria for Stockmayer fluids

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Pages 765-769 | Received 14 Jul 1989, Accepted 01 Aug 1989, Published online: 23 Aug 2006
 

Abstract

Results of Monte Carlo simulations in the Gibbs ensemble for the vapour-liquid equilibria of Stockmayer fluids are presented. The vapour-liquid curves, critical temperatures and critical densities are calculated for dipolar strengths of μ*2 = μ2/ϵσ3 = 1·0 and 2·0. Comparison of these results shows that perturbation theory over-estimates the critical point.

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