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Abstract
The equation, describing the vaporization entropies of liquid 3d-metals and taking into account the electronic distribution of 3d-metals' atoms, is received by the use of the assumption about the general character of the relationship, which characterizes the influence of transitions among degenerated states of atoms and molecules on physico-chemical quantities of liquids. It is shown that the vaporization entropies of these metals can be calculated adequately by means of this equation.