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Original Articles

Excess thermodynamic and acoustic properties for the binary mixtures of Methyl Benzoate at T = (303, 308, 313, 318 and 323) K

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Pages 272-286 | Received 25 Apr 2013, Accepted 25 Jun 2013, Published online: 07 Aug 2013
 

Abstract

Density and speed of sound data for (Methyl Benzoate + 1-Propanol), (Methyl Benzoate + 1-Butanol) and (Methyl Benzoate + 1-Pentanol) have been determined at temperatures = (303, 308, 313, 318 and 323) K. From this data, excess parameters like excess volume, VE, excess isentropic compressibility, , and excess intermolecular free length, , have been computed. The variations of these parameters with composition and temperature of the mixtures are discussed in terms of molecular interactions in these mixtures. The values of and for all the systems under study are negative.

Acknowledgements

The authors gratefully acknowledge the financial assistance from UGC DRS LEVEL III program No. F.530/1/DRS/2009 (SAP-1), dated 9 February 2009, and DST FIST program No. DST/FIST/PSI – 002/2011, dated 20 December 2011, New Delhi, to the Department of Physics, Acharya Nagarjuna University.

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