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Physics and Chemistry of Liquids
An International Journal
Volume 53, 2015 - Issue 2
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Original Articles

Determination of Abraham model solute descriptors for three dichloronitrobenzenes from measured solubilities in organic solvents

Michela BrumfieldDepartment of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX76203, USA
,
Akash WadawadigiDepartment of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX76203, USA
,
Napasorn KuprasertkulDepartment of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX76203, USA
,
Sumedha MehtaDepartment of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX76203, USA
,
Timothy W. StephensDepartment of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX76203, USA
,
Maribel BarreraDepartment of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX76203, USA
,
Jennifer De La RosaDepartment of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX76203, USA
,
Logan KennemerDepartment of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX76203, USA
,
Jocelin MezaDepartment of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX76203, USA
,
William E. Acree JrDepartment of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX76203, USACorrespondence[email protected]
&
Michael H. AbrahamDepartment of Chemistry, University College London, 20 Gordon Street, LondonWC1H OAJ, UK
 show all
Pages 163-173 | Received 07 Aug 2014, Accepted 20 Sep 2014, Published online: 06 Nov 2014
 
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Abstract

Mole fraction solubilities are reported for 1,4-dichloro-2-nitrobenzene dissolved in 24 organic solvents of varying polarity and hydrogen-bonding character. The experimental data are used to calculate Abraham solute descriptors. The calculated solute descriptors describe the experimental data to within an overall average standard deviation of 0.081 log units. Also reported in the manuscript are Abraham model solute descriptors for both 3,4-dichloro-1-nitrobenzene and 2,3-dichloro-1-nitrobenzene based on published literature data.

Acknowledgements

Akash Wadawadigi, Napasorn Kuprasertkul, and Sumedha Mehta thank the University of North Texas's Texas Academy of Math and Science (TAMS) programme for a summer research award.

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