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Spectroscopy Letters
An International Journal for Rapid Communication
Volume 54, 2021 - Issue 9
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Research Article

Hydrogen bonding and surface tension properties of aqueous solutions of tetrahydrofuran

Fang Liua Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou, China;b College of Science, Inner Mongolia University of Science and Technology, Baotou, ChinaView further author information
,
Pianpian Changc Scholl of Chemistry and Chemical Engineering, Inner Mongolia University of Science and Technology, Baotou, ChinaView further author information
,
Yuxuan Zhanga Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou, ChinaView further author information
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Mingzhe Zhanga Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou, ChinaView further author information
,
Shunli Ouyanga Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou, ChinaORCID Iconhttps://orcid.org/0000-0002-4554-4648View further author information
ORCID Icon,
Nannan Wua Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou, China;b College of Science, Inner Mongolia University of Science and Technology, Baotou, ChinaCorrespondence[email protected]
ORCID Iconhttps://orcid.org/0000-0002-8617-1446View further author information
ORCID Icon &
Hongyun Wangd Academic Affairs Office, Inner Mongolia Technical College of Mechanics and Electrics, Huhhot, ChinaView further author information
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Pages 685-692 | Received 15 Jun 2021, Accepted 10 Sep 2021, Published online: 14 Oct 2021
 
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Abstract

Significant changes observed in the tetrahydrofuran—water mixtures of different molar ratios have been determined the extent of intermolecular association via quantitative Raman experiment. The hydrogen bonding changes with the addition of tetrahydrofuran. The changes of surface tension are analyzed with hydrogen bonding in the mixtures. The result shows that the strengthening of hydrogen bonding between tetrahydrofuran and water contributes to weak the surface tension in the solutions. The correlation between surface tension and mole fractions of tetrahydrofuran is non-linear. This study provides an experimental basis for enriching the hydrogen bonding theory of multivariate aqueous solution systems.

Additional information

Funding

This work was supported by the National Natural Science Foundation of China [Grant No. 21864019], Inner Mongolia Major Basic Research Open Project [Grant No. 0406091701], Inner Mongolia University of Science and Technology Innovation Fund [Grant No. 2019YQL06], and the Natural Science Foundation of Inner Mongolia Autonomous Region of China [Grant No. 2018LH02004].

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