Fourier Transform Vibrational Spectra of Magnesium Hydrogenphosphate Trihydrate H. The 2000-370 cm⁻¹ Region

Bojn Šoptrajanov Institut za hemija, PMF, Univerzitet “Sv. Kiril i Metodij”, PO Box 162, 91001, Skopje, Macedonia; Makedonska akademija na naukite i umetnostite, Skopje, Macedonia E-mail: [email protected]

Igor Kuzmanovski Institut za hemija, PMF, Univerzitet “Sv. Kiril i Metodij”, PO Box 162, 91001, Skopje, Macedonia

Viktor Stefov1 Institut za hemija, PMF, Univerzitet “Sv. Kiril i Metodij”, PO Box 162, 91001, Skopje, Macedonia

Gligor Jovanovsk Institut za hemija, PMF, Univerzitet “Sv. Kiril i Metodij”, PO Box 162, 91001, Skopje, Macedonia

Abstract

The Fourier transform infrared and Raman spectra of newberyite, MgHPO₄·3H₂-O, were studied in the 2000-370 cm-l region. Also investigated were the spectra of a series of partially deuterated analogues. By comparing the spectra recorded at room temperature and those obtained at the boiling temperature of liquid nitrogen and by studying the spectra of the series of partially deuterated newberyite an assignment was proposed for the observed bands. The spectra are fully in line with the crystallographic data and prove that the title compound is a true crystalline hydrate and does not contain H₃O⁺ ions in its structure.

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Fourier Transform Vibrational Spectra of Magnesium Hydrogenphosphate Trihydrate H. The 2000-370 cm⁻¹ Region

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Fourier Transform Vibrational Spectra of Magnesium Hydrogenphosphate Trihydrate H. The 2000-370 cm−1 Region

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Fourier Transform Vibrational Spectra of Magnesium Hydrogenphosphate Trihydrate H. The 2000-370 cm⁻¹ Region