Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 35, 2005 - Issue 16
Submit an article Journal homepage
263
Views
8
CrossRef citations to date
0
Altmetric
Original Articles

Reductive Ring‐Opening Reaction of 2,3‐Epoxy‐1,4‐butanediones with SbCl3‐Bu4NI in the Presence of Na2S2O3·5H2O

Shinsei Sayama Department of Chemistry, Fukushima Medical University, Hikariga‐oka, Fukushima, JapanCorrespondence[email protected]
Pages 2115-2124 | Received 13 Feb 2005, Published online: 18 Aug 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

1,4‐Disubstituted 2,3‐epoxy‐1,4‐butanediones were converted to 1,4‐disubstituted 2‐hydroxy‐1,4‐butanediones with SbCl3‐Bu4NI in the presence of Na2S2O3 · 5H2O. The ring opening of terminal epoxides can also be accomplished to afford the corresponding haloalcohol with SbCl3 and tetrabutylammonium halides, Bu4NX (X=Cl, Br, I) under the same reaction conditions.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.