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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 35, 2005 - Issue 17
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Original Articles

Supported Tetramethylamonium Nitrate/Silicasulfuric Acid as a Useful Reagent for Nitration Aromatic Compounds Under Solvent‐Free Conditions

Abdol R. Hajipour Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan, Iran; Department of Pharmacology, University of Wisconsin Medical School, Madison, Wisconsin, USACorrespondence[email protected]
,
Amin Zarei Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan, Iran
,
Leila Khazdooz Pharmaceutical Research Laboratory, College of Chemistry, Isfahan University of Technology, Isfahan, Iran
&
A. E. Ruoho Department of Pharmacology, University of Wisconsin Medical School, Madison, Wisconsin, USA
Pages 2237-2241 | Received 03 Nov 2004, Published online: 18 Aug 2006
 
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Abstract

A variety of aromatic compounds are nitrated to the parent nitro aromatic compounds under solvent‐free conditions using supported tetramethylammonium nitrate/silicasulfuric acid as a useful reagent. This methodology is useful for nitration of activated and deactivated aromatic rings.

Acknowledgments

We gratefully acknowledge the funding support received for this project from the Isfahan University of Technology (IUT), IR Iran (A. R. H.), and Grant GM 33138 (A. E. R.) from the National Institutes of Health, USA. Further financial support from Center of Excellency in Chemistry Research (IUT) is gratefully acknowledged.

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