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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 35, 2005 - Issue 20
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Original Articles

Ruthenium(III) Chloride–Catalyzed Ring Opening of Epoxides with Aromatic Amines

Surya K. De Department of Medicinal Chemistry and Molecular Pharmacology, School of Pharmacy, Purdue Cancer Center, Purdue University, West Lafayette, Indiana, USACorrespondence[email protected]
&
Richard A. Gibbs Department of Medicinal Chemistry and Molecular Pharmacology, School of Pharmacy, Purdue Cancer Center, Purdue University, West Lafayette, Indiana, USA
Pages 2675-2680 | Received 18 May 2005, Published online: 22 Aug 2006
 
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Abstract

Ruthenium(III) chloride catalyzes the nucleophilic opening of epoxides by anilines, leading to the efficient synthesis of β‐amino alcohols. High regioselectivity can be considered as a noteworthy advantage of this method.

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